You can simply create an expense transaction to add a charge to your credit card account. I'd be happy to guide you through the steps.
Click the + New button, then select Expense.
Choose the payee from the drop-down.
Select the payment account and the payment method.
From the Category section, choose an expense account for the credit card charge. If you don't have it, you can create one by clicking + Add new and named it as Credit Card Charges.