If you purchase a vat, you can simply enter an expense entry with a vat on it, like 20%, automatically, the vat of that will go against the reclaim on the VAT return.
or
If you wish to enter a VAT only transaction, you can open up an expense
1st line £1.00 VAT 20% (any expense category)
2nd line -£1.00 NO VAT (same expense category as the first line)
Then you have to change the VAT amount on the bottom left