In the QuickBooks app, there's no option to add a user. However, if you want to add a user for them to upload a receipt, you can add it through a web browser or your QuickBooks Online account. Here's how:
Click the Gear icon ⚙ and select Manage users.
On the Users tab, press Add user.
Select the Roles ▼ dropdown, then choose the role you want to assign to the user.
Select the Account management settings you want to manage (only if applicable).
Hit Send invitation.
New users will receive an invite to join the company. Let them select the Let's go! link in the email for them to create a new Intuit Account or sign in if they already have one.
On the other hand, if you wanted to add a co-owner as a partner to your company. I've added an article with detailed steps to create a co-owner profile.